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Abstract Historically, clumped isotope thermometry (T(∆₄₇)) of soil carbonates has been interpreted to represent a warm‐season soil temperature based dominantly on coarse‐grained soils. Additionally, T(∆₄₇) allows the calculation of the oxygen isotope composition of soil water (δ¹⁸O_w) in the past using the temperature‐dependent fractionation factor between soil water and pedogenic carbonate, but previous work has not measured δ¹⁸O_wvalues with which to compare to these archives. Here, we present clumped isotope thermometry of modern soil carbonates from three soils in Colorado and Nebraska, USA, that have a fine‐to‐medium grain size, contain clay, and are representative of many carbonate‐bearing paleosols preserved in the rock record. At two of the three sites, Briggsdale, CO and Seibert, CO, T(∆₄₇) overlaps with mean annual soil temperature (MAST), and the calculated δ¹⁸O_woverlaps within uncertainty with measured δ¹⁸O_wat carbonate bearing depths. At the third site, in Oglala National Grassland, NE, mean T(∆₄₇) is 8–11°C warmer than MAST, and the calculated δ¹⁸O_whas a significantly higher isotope value than any observations of δ¹⁸O_w. At all three sites, even in the fall season, δ¹⁸O_wvalues at carbonate bearing depths overlap with spring rainfall δ¹⁸O_w, and there is little to no evaporative enrichment of δ²H_wand δ¹⁸O_wvalues. These data challenge long‐held assumptions that all pedogenic carbonate records a warm‐season bias, and that δ¹⁸O_wat carbonate‐bearing depths is affected by evaporative enrichment. 

ABSTRACT Ancient terrestrial sediments provide critical information about the responses of continental environments to global scale climate and tectonic perturbations, which are vastly understudied relative to marine archives. The >1 km thick Sheep Pass Formation type section in east‐central Nevada preserves non‐marine carbonates, including microbialites, and lesser siliciclastics, deposited in a tectonically active, high‐elevation basin during the latest Cretaceous through to middle Eocene time, an interval spanning major global greenhouse climate states and warming events. This study combines outcrop and hand‐sample observations, thin section petrography and X‐ray diffraction mineralogical analyses to create a facies framework and interpreted environmental evolution for the Sheep Pass Basin. Together, these observations portray the Sheep Pass Formation type section as a dynamic and highly sensitive basin due to its small size. The dominance of thrombolite boundstones compared to metazoan fossils, which sets the Sheep Pass Formation type section apart from other Palaeogene‐aged lake basins in the western United States, reflects the resilience of microbial mats compared to metazoans in this dynamic setting. The major lacustrine phase of the Sheep Pass Basin records three intervals: a shallow lake with few microbialites, followed by abundant microbialites, before the transition to a marginal setting with evaporative conditions, marking the culmination of this major lacustrine phase. The transition to a microbialite‐dominated interval was likely driven by physicochemical conditions (for example, higher alkalinity), paired with lower competition from metazoan grazers. Although the Sheep Pass Formation type section preserves environmental change in response to both tectonics and climate, similar trends in facies, mineralogy and invertebrate abundance compared to other sedimentary basins from this time suggest that global climate influenced distinct environmental shifts in the Sheep Pass Basin. This work provides a detailed sedimentological framework for a new, high‐elevation palaeoclimate record during a pivotal geological climate interval. 

Abstract. Soil water isotope datasets are useful for understanding connections between the hydrosphere, atmosphere, biosphere, and geosphere. However, they have been underproduced because of the technical challenges associated with collecting those datasets. Here, we present the results of testing and automation of the Soil Water Isotope Storage System (SWISS). The unique innovation of the SWISS is that we are able to automatically collect water vapor from the critical zone at a regular time interval and then store that water vapor until it can be measured back in a laboratory setting. Through a series of quality assurance and quality control tests, we tested whether the SWISS is resistant to both atmospheric intrusion and leaking in both laboratory and field settings. We assessed the accuracy and precision of the SWISS through a series of experiments in which water vapor of known composition was introduced into the flasks, stored for 14 d, and then measured. From these experiments, after applying an offset correction to report our values relative to Vienna Standard Mean Ocean Water (VSMOW), we assess the precision of the SWISS to be ±0.9 ‰ and ±3.7 ‰ for δ18O and δ2H, respectively. We deployed three SWISS units at three different field sites to demonstrate that the SWISS stores water vapor reliably enough that we are able to differentiate dynamics both between the sites as well within a single soil column. Overall, we demonstrate that the SWISS retains the stable isotope composition of soil water vapor for long enough to allow researchers to address a wide range of ecohydrologic questions. 

Carbonates are ubiquitous in the rock record and provide a broad array of stable isotope-based paleoclimatic proxies (i.e., δ¹⁸O, δ¹³C, ∆¹⁷O, ∆₄₇, ∆₄₈) that provide information on stratigraphy, carbon cycling, temperature, hydrology, and the altitude of ancient land surfaces. Thus, carbonates are an essential archive of environmental and topographic histories of continental terranes. However, carbonate minerals are highly susceptible to post-depositional alteration of primary isotopic values via fluid-mediated and solid-state reactions. We propose a hierarchical suite of techniques to comprehensively assess alteration in carbonates, from essential and readily accessible tools to novel, high-resolution techniques. This framework provides a means of identifying preserved textures in differentially altered samples that contain high-value environmental information. To illustrate this progressive approach, we present a case study of Tethyan nearshore carbonates from the Paleocene Tso Jianding Group (Tibet). We demonstrate the utility of each technique in identifying chemical and crystallographic indicators of post-depositional alteration at progressively finer spatial scales. For example, secondary ionization mass spectrometry (SIMS) oxygen isotope maps of micrite and bioclasts reveal significant isotopic heterogeneity due to grain-scale water-rock exchange in textures that were labeled “primary” by optical inspection at coarser spatial resolution. Optical and cathodoluminescence microscopy should be the minimum required assessment of carbonate samples used in stable isotope analyses, but supplemented when necessary by SIMS, PIC mapping, and other yet untapped technologies that may allow distinction of primary and altered fabrics at finer spatial resolutions. 

ABSTRACT Terrestrial sedimentary archives record critical information about environment and climate of the past, as well as provide insights into the style, timing, and magnitude of structural deformation in a region. The Cretaceous Newark Canyon Formation, located in central Nevada, USA, was deposited in the hinterland of the Sevier fold–thrust belt during the North American Cordilleran orogeny. While previous research has focused on the coarser-grained, fluvial components of the Newark Canyon Formation, the carbonate and finer-grained facies of this formation remain comparatively understudied. A more complete understanding of the Newark Canyon Formation provides insights into Cretaceous syndeformational deposition in the Central Nevada thrust belt, serves as a useful case study for deconvolving the influence of tectonic and climatic forces on sedimentation in both the North American Cordillera and other contractional orogens, and will provide a critical foundation upon which to build future paleoclimate and paleoaltimetry studies. We combine facies descriptions, stratigraphic measurements, and optical and cathodoluminescence petrography to develop a comprehensive depositional model for the Newark Canyon Formation. We identify six distinct facies that show that the Newark Canyon Formation evolved through four stages of deposition: 1) an anastomosing river system with palustrine interchannel areas, 2) a braided river system, 3) a balance-filled, carbonate-bearing lacustrine system, and 4) a second braided river system. Although climate undoubtedly played a role, we suggest that the deposition and coeval deformation of the synorogenic Newark Canyon Formation was in direct response to the construction of east-vergent contractional structures proximal to the type section. Comparison to other contemporary terrestrial sedimentary basins deposited in a variety of tectonic settings provides helpful insights into the influences of regional tectonics, regional and global climate, catchment characteristics, underlying lithologies, and subcrop geology in the preserved sedimentary record. 

Abstract The timing of deformation and deposition within syntectonic basins provides critical information for understanding the evolution of strain in mountain belts. In the U.S. Cordillera, contractional deformation was partitioned between the Sevier thrust belt in Utah and several structural provinces in the hinterland in Nevada. One hinterland province, the Central Nevada thrust belt (CNTB), accommodated up to ∼15 km of shortening; however, in most places, this deformation can only be bracketed between Permian and Eocene. Cretaceous deposits of the Newark Canyon Formation (NCF), which are sparsely exposed along the length of the CNTB, offer the opportunity to constrain deformation timing. Here, we present mapping and U-Pb zircon geochronology from the NCF in the Diamond Mountains, which demonstrate deposition of the NCF during proximal CNTB deformation. Deposition of the basal NCF member was under way no earlier than ca. 114 Ma, a tuff in the middle part of the section was deposited at ca. 103 Ma, and the youngest member was deposited no earlier than ca. 99 Ma. Intraformational angular unconformities and abrupt along- and across-strike thickness changes indicate that NCF deposition was related to growth of an east-vergent fault-propagation fold. Clast compositions define unroofing of upper Paleozoic sedimentary rocks, which we interpret as the progressive erosion of an anticline ∼10 km to the west. CNTB deformation was contemporaneous with shortening in the Sevier thrust belt, which defines middle Cretaceous strain partitioning between frontal and interior components of the Cordillera. Strain partitioning may have been promoted by renewed underthrusting during a period of high-flux magmatism. 

The geological record encodes the relationship between climate and atmospheric carbon dioxide (CO₂) over long and short timescales, as well as potential drivers of evolutionary transitions. However, reconstructing CO₂beyond direct measurements requires the use of paleoproxies and herein lies the challenge, as proxies differ in their assumptions, degree of understanding, and even reconstructed values. In this study, we critically evaluated, categorized, and integrated available proxies to create a high-fidelity and transparently constructed atmospheric CO₂record spanning the past 66 million years. This newly constructed record provides clearer evidence for higher Earth system sensitivity in the past and for the role of CO₂thresholds in biological and cryosphere evolution. 

Abstract Documenting the spatio‐temporal progression of deformation within fold‐thrust belts is critical for understanding orogen dynamics. In the North American Cordillera, the geometry, magnitude, and timing of contractional deformation across a broad region of Nevada known as the “Sevier hinterland” has been difficult to characterize due to minimal exposures of syn‐contractional sedimentary rocks and overprinting of Cenozoic extension. To address this, we present geologic mapping and U‐Pb zircon geochronology from three exposures of the Cretaceous Newark Canyon Formation (NCF) in central Nevada. In the Cortez Mountains, NCF deposition between ∼119 and 110 Ma is hypothesized to be related to generation of relief by thrusting/folding to the west. In the Fish Creek Range, NCF deposition between ∼130 and 100 Ma was related to motion on an east‐vergent thrust fault. In the Pancake Range, NCF deposition is bracketed between ∼129 and 66 Ma and post‐dated east‐vergent folding. We incorporate these timing constraints into a compilation of deformation timing in the Sevier hinterland. Late Jurassic (∼165 and 155 Ma) shortening, which is largely post‐dated shortening in the Luning‐Fencemaker thrust belt to the west and pre‐dated initial deformation in the Sevier fold‐thrust belt to the east, is interpreted to represent diffuse, low‐magnitude deformation that accompanied eastward propagation of the basal Cordilleran décollement. Cretaceous (∼130 and 75 Ma) hinterland shortening, which includes deformation associated with NCF deposition, was contemporaneous with shortening in the Sevier fold‐thrust belt. This is interpreted to represent long‐duration strain partitioning between the foreland and hinterland during continued coupling above the basal décollement and the progressive westward underthrusting of thick North American lower‐middle crust. 

Abstract Organic and inorganic stable isotopes of lacustrine carbonate sediments are commonly used in reconstructions of ancient terrestrial ecosystems and environments. Microbial activity and local hydrological inputs can alter porewater chemistry (e.g., pH, alkalinity) and isotopic composition (e.g., δ¹⁸O_water, δ¹³C_DIC), which in turn has the potential to impact the stable isotopic compositions recorded and preserved in lithified carbonate. The fingerprint these syngenetic processes have on lacustrine carbonate facies is yet unknown, however, and thus, reconstructions based on stable isotopes may misinterpret diagenetic records as broader climate signals. Here, we characterize geochemical and stable isotopic variability of carbonate minerals, organic matter, and water within one modern lake that has known microbial influences (e.g., microbial mats and microbialite carbonate) and combine these data with the context provided by 16S rRNA amplicon sequencing community profiles. Specifically, we measure oxygen, carbon, and clumped isotopic compositions of carbonate sediments (δ¹⁸O_carb, δ¹³C_carb, ∆₄₇), as well as carbon isotopic compositions of bulk organic matter (δ¹³C_org) and dissolved inorganic carbon (DIC; δ¹³C_DIC) of lake and porewater in Great Salt Lake, Utah from five sites and three seasons. We find that facies equivalent to ooid grainstones provide time‐averaged records of lake chemistry that reflect minimal alteration by microbial activity, whereas microbialite, intraclasts, and carbonate mud show greater alteration by local microbial influence and hydrology. Further, we find at least one occurrence of ∆₄₇isotopic disequilibrium likely driven by local microbial metabolism during authigenic carbonate precipitation. The remainder of the carbonate materials (primarily ooids, grain coatings, mud, and intraclasts) yield clumped isotope temperatures (T(∆₄₇)), δ¹⁸O_carb, and calculated δ¹⁸O_waterin isotopic equilibrium with ambient water and temperature at the time and site of carbonate precipitation. Our findings suggest that it is possible and necessary to leverage diverse carbonate facies across one sedimentary horizon to reconstruct regional hydroclimate and evaporation–precipitation balance, as well as identify microbially mediated carbonate formation.